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Choi, Y.; Umebayashi, Tsutomu; Yoshikawa, Masahito
Journal of Materials Science, 39(5), p.1837 - 1839, 2004/03
Times Cited Count:227 Percentile:97.87(Materials Science, Multidisciplinary)Carbon (C)-doped anatase TiO photocatalysts have been prepared by the oxidative annealing of TiC powders at 623 K for 50-100 hrs. From XRD and XPS analysis, it is clear that C is incorporated into O site of the TiO lattice. Diffuse reflectance spectroscopy (DRS) showed that the optical absorption edge of the C-doped anatase TiO shifted to lower energy compared with that of pure anatase TiO. The decomposition of methylene blue (MB) adsorbed on the C-doped sample was observed under a visible light range of 420-500 nm. We conclude that substitution of C for O in the TiO leads to a photocatalytic decomposition of MB under visible light irradiation.
Choi, Y.; Umebayashi, Tsutomu; Yamamoto, Shunya; Tanaka, Shigeru
Journal of Materials Science Letters, 22(17), p.1209 - 1211, 2003/09
Times Cited Count:47 Percentile:78.57(Materials Science, Multidisciplinary)no abstracts in English
Sugiharuto; Yamamoto, Shunya; Sumita, Taishi; Miyashita, Atsumi
Journal of Physics; Condensed Matter, 13(13), p.2875 - 2881, 2001/04
Times Cited Count:15 Percentile:61.85(Physics, Condensed Matter)An epitaxial TiO-anatase thin film was grown on the Si(001) substrate with SrTiO/TiN as the buffer layers by pulsed laser deposition technique under an oxygen gas supply. The characterization of the epitaxial TiO-anatase film was performed using the X-ray diffraction method. The crystallographic relationships between the TiO-anatase film and SrTiO/TiN buffer layers were analyzed by the -2 scan and pole figure measurement. The growth direction of the films was determined as / / / and their in-plane relationship // // // . The crystalline quality of TiO-anatase was examined by the rocking curve analysis. The composition of the thin film packaging was characterized by Rutherford backscattering spectrometry (RBS) using 2.0 MeV He beam.