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Journal Articles

Fabrication and characterization of C-doped anatase TiO$$_{2}$$ photocatalysts

Choi, Y.; Umebayashi, Tsutomu; Yoshikawa, Masahito

Journal of Materials Science, 39(5), p.1837 - 1839, 2004/03

 Times Cited Count:227 Percentile:97.87(Materials Science, Multidisciplinary)

Carbon (C)-doped anatase TiO$$_{2}$$ photocatalysts have been prepared by the oxidative annealing of TiC powders at 623 K for 50-100 hrs. From XRD and XPS analysis, it is clear that C is incorporated into O site of the TiO$$_{2}$$ lattice. Diffuse reflectance spectroscopy (DRS) showed that the optical absorption edge of the C-doped anatase TiO$$_{2}$$ shifted to lower energy compared with that of pure anatase TiO$$_{2}$$. The decomposition of methylene blue (MB) adsorbed on the C-doped sample was observed under a visible light range of 420-500 nm. We conclude that substitution of C for O in the TiO$$_{2}$$ leads to a photocatalytic decomposition of MB under visible light irradiation.

Journal Articles

Fabrication of TiO$$_{2}$$ photocatalysts by oxidative annealing of TiC

Choi, Y.; Umebayashi, Tsutomu; Yamamoto, Shunya; Tanaka, Shigeru

Journal of Materials Science Letters, 22(17), p.1209 - 1211, 2003/09

 Times Cited Count:47 Percentile:78.57(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Preparation of TiO$$_{2}$$-anatase film on Si(001) substrate with TiN and SrTiO$$_{3}$$ as buffer layers

Sugiharuto; Yamamoto, Shunya; Sumita, Taishi; Miyashita, Atsumi

Journal of Physics; Condensed Matter, 13(13), p.2875 - 2881, 2001/04

 Times Cited Count:15 Percentile:61.85(Physics, Condensed Matter)

An epitaxial TiO$$_{2}$$-anatase thin film was grown on the Si(001) substrate with SrTiO$$_{3}$$/TiN as the buffer layers by pulsed laser deposition technique under an oxygen gas supply. The characterization of the epitaxial TiO$$_{2}$$-anatase film was performed using the X-ray diffraction method. The crystallographic relationships between the TiO$$_{2}$$-anatase film and SrTiO$$_{3}$$/TiN buffer layers were analyzed by the $$theta$$-2$$theta$$ scan and pole figure measurement. The growth direction of the films was determined as $$rm TiO_{2}langle 001rangle$$ / $$rm SrTiO_{3}langle 001rangle$$ / $$rm TiNlangle 001rangle$$ / $$rm Silangle 001rangle$$ and their in-plane relationship $$rm TiO_{2}{110}$$ // $$rm SrTiO_{3}{100}$$ // $$rm TiN{100}$$ // $$rm Si{100}$$. The crystalline quality of TiO$$_{2}$$-anatase was examined by the rocking curve analysis. The composition of the thin film packaging was characterized by Rutherford backscattering spectrometry (RBS) using 2.0 MeV $$^{4}$$He beam.

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